Astronomers discover elusive buckyballs in space

Washington (ANI): Astronomers using NASA's Spitzer Space Telescope have, for the first time, discovered elusive carbon molecules, known as "buckyballs" in space.
 
Buckyballs - soccer-ball-shaped molecules that were first observed in a laboratory 25 years ago - are named for their resemblance to architect Buckminster Fuller's geodesic domes, which have interlocking circles on the surface of a partial sphere. Buckyballs were thought to float around in space, but had escaped detection until now.

"We found what are now the largest molecules known to exist in space. We are particularly excited because they have unique properties that make them important players for all sorts of physical and chemical processes going on in space," said astronomer Jan Cami of the University of Western Ontario, Canada, and the SETI Institute in Mountain View, Calif.

Cami's research paper about the discovery appears online in the journal Science.

Buckyballs are made of 60 carbon atoms arranged in three-dimensional, spherical structures. Their alternating patterns of hexagons and pentagons match a typical black-and-white soccer ball. The research team also found the more elongated relative of buckyballs, known as C70, for the first time in space. These molecules consist of 70 carbon atoms and are shaped more like an oval rugby ball. Both types of molecules belong to a class known officially as buckminsterfullerenes, or fullerenes.

The Cami team unexpectedly found the carbon balls in a planetary nebula named Tc 1. Planetary nebulas are the remains of stars, like the Sun, that shed their outer layers of gas and dust as they age. A compact, hot star, or white dwarf, at the center of the nebula illuminates and heats these clouds of material that has been shed.

The buckyballs were found in these clouds, perhaps reflecting a short stage in the star's life, when it sloughs off a puff of material rich in carbon. The astronomers used Spitzer's spectroscopy instrument to analyze infrared light from the planetary nebula and see the spectral signatures of the buckyballs. These molecules are approximately room temperature -- the ideal temperature to give off distinct patterns of infrared light that Spitzer can detect. According to Cami, Spitzer looked at the right place at the right time. A century from now, the buckyballs might be too cool to be detected.

The data from Spitzer were compared with data from laboratory measurements of the same molecules and showed a perfect match.

"We did not plan for this discovery," Cami said. "But when we saw these whopping spectral signatures, we knew immediately that we were looking at one of the most sought-after molecules."

Sir Harry Kroto, who shared the 1996 Nobel Prize in chemistry with Bob
Curl and Rick Smalley for the discovery of buckyballs, said, "This most exciting breakthrough provides convincing evidence that the buckyball has, as I long suspected, existed since time immemorial in the dark recesses of our galaxy."